One-dimensional segmented heteronanostructures (1D-SHs) are promising candidates in fields such as photoelectrocatalysis (PEC) and thermoelectrics. Currently, the synthesis of 1D-SHs mainly focuses on sulfides and selenides, with relatively less research on telluride materials, yet tellurides have significant application prospects in energy storage and optoelectronics. However, a simple and controlled synthesis of telluride 1D-SHs materials has always been challenging.